That 7700 is a hot motor. I had a hard time keeping the temps down in a stock rustler, the stampede is little heavier, and the bigger tires put a much larger load on the motor.
I'm just warning you, right now the batteries are your weak link. Once you go lipo that 7700 will get HOT and it may die on you. Then if it demagnetizes and you try to drive it the esc can blow quite easily. If you don't have one I would get a temp gun, and check temps often!
I would still go ahead and upgrade to lipo, but I would keep in mind that a motor will probably be your next purchase. There are plenty of motors that will push your stampede on 2s. Then you should be solid and not have to upgrade.