Castor is the direction your tires point. If there straight don't worry about it.
Castor is the relation of the tires to the ground(relative to perpendicular). It has nothing to do with whether or not the car pulls. I would check the steering trim and also the stock servo and servo saver(likely that one of them has failed). The stock e-maxx is pretty sloppy in the steering department.
easiest way to understand caster is with a bicycle.
the front fork is angled forward at the bottom which causes positive caster. it is that caster that gives you the feeling that the front tires want to return to a straight direction after a turn.
spin the handle bars around 180 degrees and try to drive and you'll see what happens.
if the tire was a stick perpendicular to the ground positive caster would be moving the top of the stick back twords the driver.
camber is moving the top of the stick in twords the center of the car or out away from the car.